Glossary Names of Common Polyatomic Ions

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Common Forms Polyatomic
Ions
Acetate ion CH3COO-
Ammonium ion NH4+
Carbonate ion CO32-
Chlorate ion ClO3-
Chlorite ion ClO2-
Chromate ion CrO42-
Cyanide ion CN-
Dichromate ion Cr2O72-
Dihydrogen Phosphate H2PO4-
Hydrogen Phosphate HPO42-
Hydroxide ion OH-
Nitrate ion NO3-
Nitrite ion NO2-
Perchlorate ion ClO4-
Permanganate ion MnO4-
Peroxide ion O22-
Phosphate ion PO43-
Phosphite ion PO33-
Sulfate ion SO42-
Sulfite ion SO32-

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Ionic compounds consist of cations (positive ions) 
and anions (negative ions). 
The nomenclature, or naming, of ionic compounds is based on the
names of the component ions. Here are the principal naming conventions
for ionic compounds, along with examples to show how they are used: 

a) [blah blah]-ide
The -ide ending is added to the name of a monoatomic ion of an element. For example;

H- is then Hydride
F- is then Fluoride
O2- is then Oxide
S2- is then Sulfide
N3- is then Nitride
P3- is then Phosphide

b) [blah blah]-ite and [blah blah]-ate
Some polyatomic anions (-) contain oxygen. These anions are called oxyanions. When an element forms two oxyanions, the one with less oxygen is given a name ending in -ite and the one with more oxgyen is given a name that ends in -ate. For example;

NO2- is then Nitrite
NO3- is then Nitrate
SO32- is then Sulfite
SO42- is then Sulfate

c) [blah blah]-ous and [blah blah]-ic
The endings -ous or -ic are added to the Latin name of the element (e.g., stannous/stannic for tin) to represent the ions with lesser or greater charge, respectively. For example;

Fe2+ is then Ferrous
Fe3+ is then Ferric
Cu+ is then Cuprous
Cu2+ is then Cupric

d) hypo-[blah blah] and per-[blah blah]
In the case where there is a series of four oxyanions, the hypo- and per- prefixes are used in conjunction with the -ite and -ate suffixes. The hypo- and per- prefixes indicate less oxygen and more oxygen, respectively. For example;

ClO- is then Hypochlorite
ClO2- is then Chlorite
ClO3- is then Chlorate
ClO4- is then Perchlorate

e) bi-[blah blah] and di-hydrogen [blah blah]
Polyatomic anions sometimes gain one or more H+ ions to form anions of a lower charge. These ions are named by adding the word hydrogen or dihydrogen in front of the name of the anion. It is still common to see and use the older naming convention in which the prefix bi- is used to indicate the addition of a single hydrogen ion. For example;

HCO3- is then Hydrogen carbonate or bicarbonate
HSO4- is then Hydrogen sulfate or bisulfate
H2PO4- is then Dihydrogen phosphate

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